Frequency spectra for fluids beyond the mean spherical approximation

Rescaled Mean Spherical Approximation for Colloidal Mixtures

In this work, the resealed mean spherical approximation (RMSA) for colloidal mixtures interacting via a DLVO-type potential is developed, and its application to suspensions of highly charged macroions is illustrated. For this purpose we introduce a simple scheme to solve the mean spherical approximation (MSA) for Yukawa mixtures with factorized coupling parameters. This scheme consists of the m...

The mean spherical approximation for a dipolar Yukawa fluid

Phase coexistence in polydisperse charged hard-sphere fluids: mean spherical approximation.

Taking advantage of the availability of the analytic solution of the mean spherical approximation for a mixture of charged hard spheres with an arbitrary number of components we show that the polydisperse fluid mixture of charged hard spheres belongs to the class of truncatable free energy models, i.e., to those systems where the thermodynamic properties can be represented by a finite number of...

Interfacial energy for nematic liquid crystals : beyond the spherical approximation

By means of a simple pseudomolecular model the surface elastic properties of nematic liquid crystals are analysed. We show that in the Maier-Saupe approximation for the intermolecular interaction and supposing the interaction volume of ellipsoidal shape, the bulk elastic constants of splay and twist are expected to be equal and different from the bend one. The dependence of the bulk elastic con...

Beyond the mean field approximation for spin glasses.

We study the d-dimensional random Ising model using a suitable type of BethePeierls approximation in the framework of the replica method. We take into account the correct interaction only inside replicated clusters of spins. Our ansatz is that the interaction of the borders of the clusters with the external world can be described via an effective interaction among replicas. The Bethe-Peierls mo...